Herein, we report the first examples of simple, readily accessible, air-stable phosphine oxides used as ligand pre-cursors for the efficient transition metal catalyzed CÿC, CÿN, and CÿS bond …

Introduction Cross-coupling reactions represent a class of synthetic transformations that involve the combination of an organometallic reagent (that has a main group metal atom in most of …

Transition Metal Catalyzed C-C Cross Coupling Reactions: An Introduction Hiroyuki Hattori Crosscoupling reactions refer to reactions that couple two different organic fragments with the …

It is well established that these reactions with second-row transition metal complexes, particularly palladium, occur by a concerted mechanism, but the mechanisms of these reactions with first …

Abstract During the previous couple of decades, transition-metal (Fe, Co, Cu, Ni, Ru, Rh, Pd, Ag, Au) catalyzed inter- and intramolecular coupling reactions have attracted huge attention for the …

Key words C–O activation, arylation, cross-coupling, secondary phos-phine oxide, nickel Transition-metal-catalyzed cross-coupling reactions have emerged as a uniquely powerful tool …

Transition metal-catalyzed cross-coupling is an efficient tool for constructing C–C, C–N and C–O bonds in organic synthesis. Ligands play a crucial role in stabilizing the active metal center …